The
equations that you'll need are P1V1
= P2V2
(Boyle's Law) and P = hρg.
(Nov 2012) A diver
works below the surface of a lake. The density of the water in the
lake is 1000 kg/m3,
the atmospheric pressure at the surface is 1.0 x 105
Pa and the gravitational field strength is 10 N/kg.
The diver inflates a balloon with air at a depth of 15 m and attaches the balloon to a tray of objects. (a) Calculate
(b) The air in the balloon occupies a volume of 0.048 m3 at the pressure calculated in (a)(ii). The diver releases the tray and the balloon and they begin to rise. The temperature of the air in the balloon does not change.
(c) State one difference between the arrangement of the molecules of water in the lake and the molecules of air in the balloon. [1] (d) When the diver releases the tray, the balloon accelerates upwards and reaches a constant speed before it arrives at the surface.
|
Background information:
- The equation for
Ideal Gas Law is PV = nRT ==> PV/T = nR where n = number of moles
of gas and R = gas constant. For an enclosed cylinder, the amount of
gas is constant and so PV/T = constant.
- For fixed amount of gas, P1V1/T1 = P2V2/T2.
Variable to keep constant | Law | Explanation using the Kinetic Theory |
Temperature is
constant,
T1 = T2 |
P1V1/T1
= P2V2/T2
P1V1 = P2V2 (Boyle's Law) |
If the gas is compressed (volume is decreased), the number of molecules per unit volume increases. This leads to increased frequency of collision of molecules on the walls of container. Therefore, the pressure increases. |
Pressure is constant,
P1 = P2 |
P1V1/T1
= P2V2/T2
V1/T1 = V2/T2 (Charles's Law) |
If the gas is heated, the molecules move faster (the KE of the molecules increases). This leads to increased frequency of collision of molecules on the walls of the container. The gas expands and pushes the piston so as to maintain the initial pressure. |
Volume is constant,
V1 = V2 |
P1V1/T1
= P2V2/T2
P1/T1 = P2/T2 (Lussac's Law) |
If the gas is heated, the molecules move faster (the KE of the molecules increases). This leads to increased frequency of collision of molecules on the walls of the cylinder. Therefore, the pressure in the fixed volume of container increases. |
Note: V1/T1 = V2/T2 and P1/T1 = P2/T2 are not in the current syllabus.
Sketch out a diagram to understand the problem.
(a) (i) Pressure due to the water
= hρg
= 15 m x 1000 kg/m3 x 10 N/kg [1]
= 1.5 x 105 Pa (2 significant figures) [1]
(ii) Total pressure
= Patm + hρg
= 1.0 x 105 Pa + 1.5 x 105 Pa
= 2.5 x 105 Pa (2 significant figures) [1]
(b) (i) P1V1 = P2V2 (Boyle's Law)
(2.5 x 105 Pa)(0.048 m3) = (1.0 x 105 Pa)V2 [1]
V2 = 0.12 m3 (2 significant figures) [1]
(ii) The balloon is larger at the surface than at the bottom of the lake. [1] The number of molecules per unit volume decreases as the balloon rises. [1] The frequency of collision of molecules on the inner surface of the balloon decreases. [1] Therefore, the pressure in the balloon is less at the surface than at the 15-m depth.
(c) The water molecules are very close together while the air molecules are very far apart. [1]
(d) (i) ∑F = ma
U – W – R = ma where U = upward thrust, W = weight, R = water resistance [1]
When U > W + R, a > 0 i.e. The balloon accelerates. [1]
As the balloon speeds up, R increases in magnitude.
Eventually, when U = W + R, a = 0 i.e. The balloon travels with a constant speed. [1]
(ii) (See diagram)
Try these questions before you check with the answers below.
1. (Nov 2013) The conditions at the bottom and at the surface of a lake are given.
Bottom of lake | Surface of lake | |
Temperature | 10 ºC | 10 ºC |
Pressure | 500 kPa | 100 kPa |
A bubble of volume 1.0 cm3 forms at the bottom of the lake. What is the volume of the bubble as it reaches the surface?
A 0.20 cm3
B 0.25 cm3
C 4.0 cm3
D 5.0 cm3
2. (Jun 2011) (a) Explain using ideas about molecules
- why a balloon
filled with gas expands when heated
- why a balloon
filled with water expands very little when heated
- State one
assumption that you have made in your calculation. [1]
Answers: 1. P1V1 = P2V2 ==> (500 kPa)(1.0 cm3) = (100 kPa)V2 ==> V2 = 5.0 cm3. 2. (a) (i) When heat is supplied to the gas, the gas molecules move faster (The molecules have greater kinetic energy). The frequency of collision on the inner surface of the balloon increases. Therefore the balloon expands to maintain the initial pressure. (ii) When liquid water is heated, the water molecules push against one another with more force. The liquid water expands. But it expands very little because the water molecules are still very close together. (b) (i) P1V1 = P2V2 ==> (3.0 x 105 Pa)(2.0 cm3) = (1.0 x 105 Pa)V2 ==> V2 = 6.0 cm3. (ii) Assumption: Temperature remains constant when the bubble rises from the bottom of the lake to the surface.
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